مشخصات پژوهش

صفحه نخست /First electrospun immobilized ...
عنوان
First electrospun immobilized molybdenum complex on bio iron oxide nano fi ber for green oxidation of alcohols
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
Nanocatalyst Nanofiber Composites polymers
چکیده
Bio iron oxide was synthesized from natural Sesbania sesban plant and modified by a molybdenum complex (Fe2O3/MoSB). Fe2O3/MoSB was deposited on polyvinyl alcohol (PVA) using a conventional single nozzle electrospinning technique (PVA/Fe2O3/MoSB). TEM, SEM, AFM, FT-IR, TGA, EDAX, and elemental analysis were used to determine fiber compositional information. The catalytic efficiency of electrospun PVA/Fe2O3/MoSB nanofiber in the oxidation of alcohols was exploited. The green reactions were conducted at solvent free conditions as a green media in the presence of H2O2 to have the desired aldehydes and tert-butyl hydrogen peroxide to obtain acid products in high yields and excellent selectivity. The survival of this nanocomposite was investigated and it could be reused and recycled in consecutive runs
پژوهشگران صدیقه عباسپور (نفر اول)، آتنا نعیمی (نفر دوم)، هوشنگ حمیدیان (نفر سوم)