University of Jiroft | Mahboube Shirani

Research

Title	Development of a rapid efficient solid-phase microextraction: An overhead rotating flat surface sorbent based 3-D graphene oxide/ lanthanum nanoparticles @ Ni foam for separation and determination of sulfonamides in animal-based food products
Type	Article
Keywords	Solid phase microextraction Overhead rotating flat surface sorbent Graphene oxide/lanthanum nanoparticles Nickel foam Sulfonamides Animal based foodstuffs
Researchers	Mahboube Shirani, Ehsan Parandi, Hamid Rashidi Nodeh, Behrouz Akbari-adergani, fatemeh shahdadi

Abstract

In this study, an overhead rotating flat surface sorbent based solid-phase microextraction was developed as a rapid and efficient method for simultaneous separation and determination of sulfonamides in animal based-food products. 3D graphene oxide/ lanthanum nanoparticles @ Ni foam was introduced as a novel selective sorbent. SEM-EDX and FT-IR techniques were applied for characterization of the sorbent. At optimum conditions, the linear ranges of 0.4–700.0 (μg L-1), 0.3–900.0 (μg L-1), and 0.25–500 (μg L-1) and the enrichment factors of 606.8, 604.3, 608.9 were obtained for SDZ, SMX, and SMZ, respectively. The LOD (S/N=3) of 0.14, 0.11, 0.08 (μg L-1) were achieved for SDZ, SMX, and SMZ, respectively. The intra-day and inter-day precision (%) (five days, n=7) for the concentration of 100 μg L-1 were less than 4.3 and 3.8, respectively. The recoveries over 90.0 % revealed high capability of the method for utilization in complex matrixes.