May 18, 2024

neda Seyedi

Academic rank: Instructor
Address:
Education: PhD. in شیمی
Phone:
Faculty:

Research

Title
Introduction of PdCl2 supported on tartaric acid modified magnetite nanoparticles (Fe3O4@TA-Pd) as a novel catalytic system in Suzuki–Miyaura coupling reaction
Type Article
Keywords
Fe3O4@TA-Pd PdCl2 Tartaric acid Magnetic Suzuki–miyaura cross-coupling reaction
Researchers Najmeh Amirmahani, Nosrat O. Mahmoodi, mohammad malakootian, abbas Pardakhty, neda Seyedi

Abstract

In this paper, a new magnetically separable catalytic system based on Palladum (Pd) encapsulated with tartaric acid (TA) as a linker (Fe3O4@TA-Pd) is introduced in which TA as a hydroxy organic acid grafted onto the Fe3O4 nanoparticles (Fe3O4 NPs) readily forms complexes with Pd2+. To assess the catalytic capability of the prepared catalyst bearing Pd chelated with TA, it was exploited for achieving some biaryl compounds through Suzuki–Miyaura cross-coupling reaction of aryl halides with phenylboronic acid (PhB(OH)2). This catalyst was reused up to 7 runs with minimizing the change in its activity. Convenient preparation, easy separation and recoverability of this catalyst, facile and efficient transformation to biaryl products along with relatively excellent yields are of the superiorities of this catalyst.