14 اردیبهشت 1403

آتنا نعیمی

مرتبه علمی: دانشیار
نشانی: جیرفت، کیلومتر 8 جاده بندرعباس، دانشگاه جیرفت
تحصیلات: دکترای تخصصی / شیمی معدنی
تلفن:
دانشکده: دانشکده علوم پایه

مشخصات پژوهش

عنوان
SnO2@ZnO nanocomposites doped polyaniline polymer for high performance of HTM‑free perovskite solar cells and carbon‑based
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
Perovskite, nanocomposite
پژوهشگران فائزه ارجمند، زهرا گلشنی، شهاب مقصودی، آتنا نعیمی، جمیل الذین فاطمی

چکیده

Herein, at frst, green SnO2@ZnO nanocomposites were synthesized using Calotropis plant extract as an electron transfer material (ETM) to fabricate low-temperature-processed perovskite solar cells (PSCs). Then, the polyaniline (PANI) polymer was applied as an efcient additive to improve perovskite flm quality. Under the efects of the small content of PANI additive, the quality of perovskite flms is enhanced, which showed higher crystallinity in (110) crystal plane; also, the perovskite grains were found to be enlarged from 342 to 588 nm. The power conversion efciency (PCE) of the prepared PSCs with SnO2@ZnO.PANI nanocomposites electron transfer layer (ETL) increased by 3.12%, compared with the PCE of SnO2@ZnO nanocomposites. The perovskite devices using SnO2@ZnO. PANI nanocomposites ETL have shown good stability during 480 h of tests. Furthermore, the optimal PSCs were fabricated by the mp-TiO2/SnO2@ZnO.PANI nanocomposites as ETL, which has a power conversion efciency of 15.45%. We expect that these results will boost the development of lowtemperature ETL, which is essential for the commercializing of high-performance, stable, and fexible perovskite solar cells