15 اردیبهشت 1403

آتنا نعیمی

مرتبه علمی: دانشیار
نشانی: جیرفت، کیلومتر 8 جاده بندرعباس، دانشگاه جیرفت
تحصیلات: دکترای تخصصی / شیمی معدنی
تلفن:
دانشکده: دانشکده علوم پایه

مشخصات پژوهش

عنوان
Self‐assembled nanoporphyrins in the presence of gold bio‐ nanoparticles as heterogeneous nano‐biocatalyst for green production of aldehydes and ketones
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
biological catalyst, macromolecules, porphyrin
پژوهشگران محمود طاهری بزمی، آتنا نعیمی، سمیرا سعیدنیا، مهدی هاتفی

چکیده

We report a simple and facile self‐assembly method for the successful fabrication of a biological macromolecule, MnTPPCl (manganese(III) chloride 5,10,15,20‐tetraphenylporphyrin), intercalated into gold nanoparticles using the cooperative effects of Sesbania sesban plant. This biohybrid was characterized using various techniques for further investigation. The catalytic activity of this biological hybrid was considered in the production of aldehydes and ketones from primary and secondary alcohols, respectively. Excellent conversions and selectivties were obtained applying Au@MnTPPCl colloidal nanocomposite and NaIO4 as an oxygen donor in ethanol.