The development of highly efficient and stable photovoltaic devices hinges significantly on optimizing charge carrier
dynamics within photoactive layers. Multi-walled carbon nanotube (MWCNT) reinforced titanium dioxide (TiO2)
nanocomposites have emerged as a pivotal advancement in next-generation solar cell architectures, including Dye-
Sensitized Solar Cells (DSSCs), Perovskite Solar Cells (PSCs), and hybrid systems. This paper reviews the strategic
incorporation enhance overall device performance. The
primary mechanism involves the highly conductive nature of MWCNTs, which establishes efficient percolation
pathways, dramatically improving electron mobility and facilitating rapid charge transport away from the interfaces.
Furthermore, MWCNTs act as effective traps or sinks for photogenerated electrons, suppressing detrimental
recombination processes occurring at the semiconductor electrolyte or semiconductor hole-transporting material
interfaces. The synergistic interplay between the high surface area and excellent charge-accepting properties of TiO2
and the one-dimensional conductivity of MWCNTs results in a broader light absorption range and superior charge
collection efficiency. Optimization of the MWCNT loading concentration is critical to maximize these benefits while
avoiding excessive aggregation, which can impede charge transfer. This review highlights the tangible improvements
in power conversion efficiency ( ) attributable to the enhanced charge transport and reduced charge recombination
kinetics afforded by these advanced nanocomposites.