Conductive polymers (CPs) have emerged as revolutionary materials in the field of photovoltaics, offering
significant advantages over traditional inorganic semiconductors, particularly in terms of mechanical flexibility, lowcost
solution processability, and tunable electronic properties. This paper provides a comprehensive review of the
applications of CPs, such as polyaniline (PANI), poly(3,4-ethylenedioxythiophene) (PEDOT), and poly (p-phenylene
vinylene) (PPV) derivatives, in various solar cell architectures, including bulk heterojunction (BHJ) polymer solar
cells (PSCs), dye-sensitized solar cells (DSSCs), and perovskite solar cells (PSCs). We discuss the role of CPs as
active layer components, hole transporting materials (HTMs), and electron-blocking layers, emphasizing how their
structural modifications influence charge carrier mobility, energy level alignment, and overall device efficiency and
stability. Challenges related to long term operational stability and intrinsic power conversion efficiencies (PCEs) are
also addressed, alongside emerging strategies to overcome these limitations through advanced morphology control
and composite material development. The potential for low-cost, large-area flexible solar energy harvesting
underscores the continuing relevance of CPs in sustainable energy technology.