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Keywords
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Ultrasound, Nano Chemosensor, Triazine based Schiff base, DFT, Sol-gel
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Abstract
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This work introduces novel selective and sensitive optical sensor based on a nano sized triazine based
Schiff base (H2L) immbolized on a transparent glass substrate through the sol–gel process to detection of copper (II)
ions in aqueous solutions. This sensor can determine the copper (II) in the range of 8.54×10−8 to 1.0×10−5 mol L-1
with a low detection limit of 1.53 × 10-8 mol L-1. The optimized geometry of H2L and its copper complex was obtained
based on DFT/B3LYP levels of theory with B3LYP/6-311+G(d,p) and LANL2DZ/6-311+G(d,p) basis sets respectively.
The calculated electronic properties of them including the molecular orbital, Mulliken population analysis, contour of
electrostatic potential, and molecular electrostatic potential map confirmed the behavior of the sensor. Some
advantage of the fabricated sensor such as high selectivity, sensitivity, short response time, easy production, fast
regeneration, low cost, being portable and user friendly can make it a good choice to detection of Cu(II) ion in various
application. The suggested sensor was revealed excellent sensitivity in the natural samples that confirmed by
Inductively Coupled Plasma-Mass (ICP) spectrometry method.
Key
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