University of Jiroft | Mahboobeh Zahedifar

Research

Title	Synthesis of tetramethylquinoline‐2,4‐diamine using FeNi3/ KCC‐1/APTPOSS‐supported copper cyclam and salen complex as a reusable catalyst
Type	Article
Keywords	copper(II), KCC‐1, magnetic nanoparticles, salen, tetramethylquinoline‐2,4‐diamine
Researchers	Seyed Mahdi Saadat, Rahele Zhiani, Mahboobeh Zahedifar, Seyed Mohsen Sadeghzadeh

Abstract

The potential application of an efficient, easily recoverable and reusable magnetically separable FeNi3/KCC‐1/APTPOSS nanoparticle‐supported Cu(II) cyclam and salen complex catalyst for the synthesis of tetramethylquinoline‐ 2,4‐diamine was investigated. The FeNi3/KCC‐1/APTPOSS/Cyclam@Salen/ Cu(II) magnetic nanoparticles were thoroughly characterized using various techniques. This catalyst was utilized in the direct and selective chemical reaction of 1,3‐dichlorovinamidinium⋅PF6 with aniline for the synthesis of tetramethylquinoline‐2,4‐diamine. The recycled catalyst was analysed using inductively coupled plasma mass spectrometry, which showed only minor changes in the morphology after the reaction, thus confirming the robustness of the catalyst