16 اردیبهشت 1403

راضیه رضوی پاریزی

مرتبه علمی: دانشیار
نشانی:
تحصیلات: دکترای تخصصی / شیمی فیزیک
تلفن:
دانشکده: دانشکده علوم پایه

مشخصات پژوهش

عنوان
Eco‑friendly synthesis by Rosemary extract and characterization of Fe3O4@SiO2 magnetic nanocomposite as a potential adsorbent for enhanced arsenic removal from aqueous solution: isotherm and kinetic studies
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
Arsenic elimination · Magnetic adsorbents · Nanostructures · Isotherm · Kinetics
پژوهشگران راضیه رضوی پاریزی، مهناز امیری، مسعود صلواتی نیاسر

چکیده

Recently, arsenic polluted groundwater water has become a big concern because it damages the health of humans as well as many dangers to drinking water supplies and ecosystems. Hence, an efective technique of simultaneous oxidation of As(III) to As(V), and removal of As(V) from water has gained growing attention. In this study, Rosemary extract was used in a precipitation/sonication one-pot method to synthesize Fe3O4/SiO2 nanocomposite. The capacity of the Fe3O4/SiO2 nanocomposite to remove arsenic from water as an adsorbent was studied. XRD, SEM, EDX, VSM, and FTIR techniques were used to characterize the fnal product. XRD pattern presented the absence of any impurities and minor, and SEM identifed low agglomerated spherical particles. Reported image produced via nanosizer analysis depicts narrow size distribution. The saturation magnetization rate was 28.32 emu/g, suitable for collecting the nanocomposite from water by the magnetic feld. Moreover, the isotherm and kinetics of arsenic removal from the nanocomposite were examined further. The Langmuir model best suited the acquired data, confrming an adsorption capacity of approximately 49 mg g−1. Additionally, the adsorption kinetic was identifed to be in line with the pseudo-second-order kinetic model. Therefore, the synthesized magnetic nanocomposite is an efective adsorbent to remove arsenic from water.