|
کلیدواژهها
|
Soil contamination, Machine learning, SHAP analysis, Remote sensing, Dust-prone soils
|
|
چکیده
|
Soil contamination by potentially toxic metals (PTMs) in dust-prone regions poses significant risks to
public health and the environment. Accurate prediction of their spatial distribution and identification of
controlling factors are essential for effective risk mitigation. This study determined the most accurate
model–scenario combinations for predicting arsenic (As), cadmium (Cd), chromium (Cr), nickel (Ni),
lead (Pb), and zinc (Zn) concentrations in the northwestern Jazmourian Basin, southeastern Iran. PTMs
and soil properties were measured in 104 surface soil samples (0–10 cm) in the laboratory. Modeling
was performed using Random Forest (RF) and Extreme Gradient Boosting (XGB) under five scenarios
based on soil properties (SP), anthropogenic factors (AF), geo-based factors (GBF), meteorological
elements (ME), and remote sensing auxiliary data (RSAD). Critical regions were identified by combining
binary maps of the six PTMs, classified according to their crustal mean concentrations, where higher
cumulative values indicated multi-metal contamination zones. The contribution of controlling factors
was quantified using Shapley Additive Explanations (SHAP). Optimal predictions for As and Cr were
obtained using XGB–Scenario (I) (RSAD) and XGB–Scenario (III) (RSAD + ME + GBF) with R² values of
0.40 and 0.55, respectively. Higher R² values of 0.52, 0.34, and 0.65 were achieved for Cd, Pb, and
Zn using XGB–Scenario (V) (RSAD + ME + GBF + AF + SP). RF–Scenario (V) provided the best spatial
prediction for Ni (R² = 0.31). Human settlements in the central region were identified as critical zones.
SHAP analysis showed that RSAD contributed most to predicting As and Zn, whereas GBF, SP, and ME
were dominant for Cr, Ni, Cd, and Pb. Among predictive variables, inverted difference vegetation index
(IPVI), band ratio (3/4), geological formations, slope, silt, and wind speed were key controlling factors.
These findings provide valuable guidance for environmental planning and soil contamination risk
reduction in dust-prone areas.
|